银离子比色检测技术研究进展

doi:10.19586/j.2095-2341.2023.0127

生物技术进展 ›› 2024, Vol. 14 ›› Issue (1): 111-119.DOI: 10.19586/j.2095-2341.2023.0127

• 进展评述 • 上一篇

银离子比色检测技术研究进展

杨敏¹(), 褚厚娟²^,³, 朱龙佼¹, 胡清华²^,³, 许秀丽⁴, 张峰⁴, 谢语诗¹, 许文涛¹, 杨松林²^,³()

^1.中国农业大学营养与健康系，食品精准营养与质量控制教育部重点实验室，北京 100083
^2.中国航天员中心，北京 100094
^3.人因工程全国重点实验室，北京 100094
^4.中国检验检疫科学研究院，北京 100176

收稿日期:2023-10-17 接受日期:2023-11-29 出版日期:2024-01-25 发布日期:2024-02-05
通讯作者: 杨松林
作者简介:杨敏 E-mail: yangm61012@163.com；
基金资助:
63919部队基础科研项目(2022-JYAUOX-F5003);北京市设施蔬菜创新团队项目(BAIC01)

Research Progress on Silver Ion Colorimetric Detection

Min YANG¹(), Houjuan CHU²^,³, Longjiao ZHU¹, Qinghua HU²^,³, Xiuli XU⁴, Feng ZHANG⁴, Yushi XIE¹, Wentao XU¹, Songlin YANG²^,³()

^1.Key Laboratory of Precision Nutrition and Food Quality，Department of Nutrition and Health，China Agricultural University，Beijing 100083，China
^2.China Astronaut Research and Training Center，Beijing 100094，China
^3.National Key Laboratory of Human Factors Engineering，Beijing 1000944，China
^4.Chinese Academy of Inspection and Quarantine，Beijing 100176，China

Received:2023-10-17 Accepted:2023-11-29 Online:2024-01-25 Published:2024-02-05
Contact: Songlin YANG

摘要/Abstract

摘要：

由于银离子（Ag⁺）会威胁人类健康和生态系统平衡，其检测在环境和食品领域引起了广泛关注。比色法是检测Ag⁺最常用的方法之一，具有简单、易操作、可现场快速检测等优点。传感机理以及显色材料的发展是比色法领域的重要研究方向。综述了Ag⁺比色检测技术的显色机理及其传感策略，将显色机理分为三类，包括酶催化、等离子体共振和化学显色，并对相应的显色材料进行了概括。讨论了Ag⁺检测的传感机理、传感性能和实际样品应用，并总结了目前Ag⁺比色法检测的挑战和前景，旨在帮助读者更好地理解Ag⁺比色法的原理，推动重金属离子快速检测技术的发展。

关键词: 比色法, Ag⁺, 显色机理, 纳米材料, DNA

Abstract:

Due to the threat of silver ions （Ag⁺） to human health and ecosystems balance， the detection of Ag⁺ has attracted much attention in the environmental and food fields. The colorimetric method is one of the most commonly used methods for the detection of Ag⁺， which has advantages of simplicity， convenience of use， and quick on-site detection. The sensing mechanism and color development materials is an important research direction in the field of colorimetric method. In this paper， we reviewed the colorimetric principles and sensing strategies of Ag⁺colorimetric sensor. We first classified the colorimetric principles into three categories， including enzyme catalysis， localized surface plasmon resonance and chemical coloration， and the corresponding color development materials were also outlined. Then the sensing mechanism， sensing performance and practical sample applications for Ag⁺ detection were discussed. Finally， the current challenges and prospects of Ag⁺ colorimetric detection were also summarized. The purpose of this work was to promote the development of rapid detection technology for heavy metal ions and also assisting readers in better comprehending the principle of Ag⁺ colorimetric method.

Key words: colorimetric, Ag⁺, colorimetric principles, nanomaterials, DNA

中图分类号:

Q-33

杨敏, 褚厚娟, 朱龙佼, 胡清华, 许秀丽, 张峰, 谢语诗, 许文涛, 杨松林. 银离子比色检测技术研究进展[J]. 生物技术进展, 2024, 14(1): 111-119.

Min YANG, Houjuan CHU, Longjiao ZHU, Qinghua HU, Xiuli XU, Feng ZHANG, Yushi XIE, Wentao XU, Songlin YANG. Research Progress on Silver Ion Colorimetric Detection[J]. Current Biotechnology, 2024, 14(1): 111-119.

图/表 5

图1 银离子比色检测技术的显色原理及传感策略

Fig. 1 The colorimetric principles and sensing strategies of Ag+ colorimetric detection

图2 基于MB与适配体相互作用的Ag+比色检测原理图[32]

Fig. 2 The schematic diagram of Ag+ colorimetric detection based on the interaction between MB and aptamer[32]

图3 基于谷胱甘肽刻蚀AuNP@MnO2纳米粒子比色检测银离子原理图[41]

Fig. 3 The schematic diagram of Ag+ colorimetric detection based on etching AuNP@MnO2 nanoparticles with glutathione[41]

图4 基于NBD的比色化学传感器NPB用于检测Ag+ [20]

Fig. 4 NBD-based colorimetric chemosensor NPB for detecting Ag+ [20]

表1 银离子不同比色检测方法的比较

Table 1 Comparison of different colorimetric detection methods for Ag+

	材料	传感机制	线性范围	检测限	实际样品	参考文献
DNA	AuNPs、 Exo Ⅲ、C-rich ssDNA	LSPR	0.057∼57.000 nmol·L^-1	39 fmol·L^-1	河水	[33]
DNA	G-四链体-Hemin脱氧核酶	酶催化	2×10^-8~2×10^-6mol·L^-1	7 nmol·L^-1	/	[35]
纳米材料	Ch-PtNPs	酶催化	5~1 000 nmol·L^-1	4 nmol·L^-1	自来水和湖水	[36]
	DSP-AuNPs	LSPR	0.50~3.00 μmol·L^-1、3.00~35.00 μmol·L^-1	0.13 μmol·L^-1	天然水和来自校园内排水沟的水	[40]
	Ti3C2 MXene	LSPR	2~200 μmol·L^-1	0.615 μmol·L^-1	自来水	[47]
化学分子	磺胺基复合物	化学显色	/	2.42 μmol·L^-1	/	[21]
化学分子	N,N-二甲基-7-硝基苯并[c][1-2,5]噁二唑-4-胺	化学显色	0~4.0 × 10^-5 mol·L^-1	3.60 μmol·L^-1	/	[20]

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银离子比色检测技术研究进展

Research Progress on Silver Ion Colorimetric Detection

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